[仁科 辰夫]
[産学官民連携のための研究者総覧へ]
［TOPへ戻る］
★
◎山形大学／大学院理工学研究科／生体センシング機能工学専攻／生体計測科学講座
仁科 辰夫（NISHINA Tatsuo）
1958年生 ／助教授 【電気化学，品質管理，情報化学】
○研究テーマ： (1) 燃料電池の基礎電気化学の研究
(2) 新型二次電池用新規電池材料の開発と物性評価
(3) 表面酸化物薄膜の高度利用技術
(4) 誘電泳動現象を用いた新規分析機器の開発
○主な授業科目： 応用化学演習II、無機・分析化学応用実験、応用化学実験I、電気化学、界面電子化学特論、電子移動化学特論、生体化学計測特論、電磁波生体計測特論
○学会・社会活動等： 米国電気化学会、国際電気化学会、日本化学会、電気化学会編集委員会幹事、電気化学会(東北支部幹事)、表面技術協会(東北支部幹事)
産業技術総合研究所溶融炭酸塩形燃料電池連携研究体推進委員会委員、
石油代替電源用新素材試験･評価方法標準化調査研究委員会燃料電池分科会委員、
日本規格協会東北支部品質管理と標準化セミナー(QSS)講師、
研究業績
○リチウム電池駆動用電解液中におけるアルミニウムの不働態化（共著）,Electrochemistry, Vol. 69, No.9, pp.670-680(2001)
○溶融炭酸塩型燃料電池のガス電極反応の研究，博士(工学)取得論文 ,東北大学(1994)
○Gas Electrode Reactions in Molten Carbonate Media. Part I. Exchange Current Density of Oxygen Reduction in (Li+K)CO3 Eutectic at 650oC.（共著）,J. Electroanal. Chem., 206, 229-239(1986)
○Gas Electrode Reactions in Molten Carbonate Media. Part II. Oxygen Reduction Kinetics on Conductive Oxide Electrodes in (Li+K)CO3 Eutectic at 650oC.（共著）,J. Electroanal. Chem., 206, 241-252(1986)
○Gas Electrode Reactions in Molten Carbonate Media. Part III. Temparature Dependence of Oxygen Reduction Kinetics in (Li+K)CO3 Eutectic.（共著）,J. Electroanal. Chem., 209, 125-133(1986)
○溶融炭酸塩中での溶存酸素種に関する電位−pO2-図と酸素還元反応機構（共著）,電気化学，56, 111-116(1988)
○クーロスタット法における積分解析法とその溶融炭酸塩中での酸素還元反応への適用（共著）,電気化学，56, 419-424(1988)
○溶融アルカリ炭酸塩中の水素および酸素ガス電極反応（共著）,日本化学会誌，1988(8), 1297-1307(1988)
○Electrochemical Characterization of in situ NiO Formation in a Molten Carbonate（共著）,J. Electroanal. Chem., 263, 87-96(1989)
○Gas Electrode Reactions in Molten Carbonate Media. Part IV. Electrode Kinetics and Mechanism of Hydrogen Oxidation in (Li+K)CO3 Eutectic（共著）,J. Electrochem. Soc., 137, 1112-1121(1990)
○複合電着被覆法による溶融炭酸塩型燃料電池用ガス拡散型多孔質アノードの作成 （共著）,電気化学，58, 354-359(1990)
○溶融炭酸塩中における in situ NiO の生成に関する電気化学的考察（共著）,電気化学，58, 442-447(1990)
○溶融炭酸塩中における Ni-Cu 系合金電極上での水素電極反応の速度論的解析（共著）,電気化学，58, 856-861(1990)
○in situ XRD測定法による銅の無電解析出過程の検討（共著）,表面技術，43, 451-456(1992)
○熱重量分析による溶融炭酸塩中でのNiO生成過程の研究（共著）,日本化学会誌，1992(9), 897-901(1992)
○Gas Sensing Using Microring-Ring Electrodes. Application to a Gas Chromatographic Detector （共著）,Denki Kagaku, 61, 825-826(1993)
○Kinetic Study of Oxygen Reduction in Molten Li2CO3+K2CO3 under Pressurized Conditions（共著）,Electrochim. Acta, 38, 2405-2411(1993)
○Electrochemical Corrosion Studies on Molten Carbonate Fuel Cell Components（共著）,Molten Salt Forum, 1-2, 273-284(1993)
○Electroreduction of Oxygen under Pressurized Conditions in Molten Carbonate Media（共著）,Molten Salt Forum, 1-2, 303-318(1993)
○Gas Electrode Reactions in Molten Carbonate Media. Part V. Electrochemical Analysis of the Oxygen Reduction Mechanism at a Fully Immersed Gold Electrode（共著）,J. Electrochem. Soc., 141, 1191-1198(1994)
○In Situ Low Incident Angle XRD Technique with Electrochemical Methods -Application to Deuterium Charging into Palladium Cathode-（共著）,Hyomen Gijutsu, 45, 956-957(1994)
○Kinetic Studies of H2S Impurity Effects on Hydrogen Oxidation in Molten (Li+K)CO3（共著）,J. Electroanal. Chem., 369, 161-168(1994)
○Oxide Electrodes in Molten Carbonates. I. Electrochemical Behaviour of Nickel in Molten Li+K and Na+K Carbonate Eutectics.（共著）,J. Electroanal. Chem., 391, 125-132(1995)
○Oxide Electrodes in Molten Carbonates. II. Electrochemical Behaviour of Cobalt in Molten Li+K and Na+K Carbonate Eutectics.（共著）,J. Electroanal. Chem., 391, 133-139(1995)
○Kinetic Study of Oxygen Reduction in Molten Li2CO3+Na2CO3 under Pressurized Conditions. （共著）,Electrochim. Acta, 40, 1927-1932(1995)
○マイクロ電極を用いる有機電解液中でのリチウム析出・溶解挙動の評価（共著）,表面技術，46, 941-945(1995)
○Electrochemical Measurements of Single Particles of Pd and LaNi5with a Microelectrode Technique.（共著）,J. Electroanal. Chem., 396, 169-173(1995)
○Water Effect on Oxygen Reduction in Molten (Li＋K)CO3 Eutectic（共著）,J. Electroanal. Chem., 408, 181-187(1996)
○Transient Response Analysis on an 100cm2 Class Molten Carbonate Fuel Cell（共著）,DENKI KAGAKU, 64(6), 486-490(1996)
○Optimization of Cathode Gas Compositions for MCFC Using Simplified Thin Film Model（共著）,DENKI KAGAKU, 64(6), 513-518(1996)
○A Kinetic Study of Spike peaks Observed under Pressurized Oxidant Gas Atmospheres in Molten Alkali Carbonates（共著）,J. Electrochem. Soc., 143, 2315-2318(1996)
○In-situ NiO dissolution behavior in (Li+Na)CO3 melts under pressurized oxidant gas atmospheres（共著）,J. Power Sources, 62, 145-147(1996)
○In Situ Conductivity Measurements of LiCoO2 Film during Lithium Insertion/Extraction by Using Interdigitated Microarray Electrodes（共著）,J. Electrochem. Soc., 143, 3157-3160(1996)
○Determination of Chemical Diffusion Coefficients in Metal Hydride Particles with a Microelectrode Technique（共著）,J. Electrochem. Soc., 144, 1273-1277(1997)
○In situ Raman spectroscopic study of LiX CoO2 electrodes in propylene carbonate solvent systems（共著）,J. Power Sources, 68, 333-337(1997)
○Application of the microelectrode technique to the kinetic study of lithium deposition/dissolution and alloying in organic solutions（共著）,J. Power Sources, 68, 483-486(1997)
○Microelectrode investigation of the lithium redox behavior in plasticized polymer electrolytes（共著）,J. Power Sources, 68, 487-491(1997)
○Electrochemical characterization of thin-film LiCoO2 electrodes in propylene carbonate solutions（共著）,J. Power Sources, 68, 487-491(1997)
○Electrode Kinetics of Oxygen Reduction in Molten Carbonates（共著）,Molten Salt Forum, 5-6, 77-78(1998)
○Transient Response Analysis of Current Interrupt and Electrochemical Impedance Spectroscopy on an 100 cm2 Class Molten Carbonate Fuel Cell（共著）,Molten Salt Forum, 5-6, 79-82(1998)
○Characterization of a 100 cm2 Class Molten Carbonate Fuel Cell with Current Interruption（共著）,J. Electrochem. Soc., 145, 2747-2751(1998)
○Effect of Hetero-contacts at Active Material Conductive Additives on Lithium Intercalation/Deintervalation of LiCoO2（共著）,Denki Kagaku, Vo.66, No.12, pp.1248-1252(1998)
○マイクロ電極を用いる有機電解液と金属の安定性の評価（共著）,Electrochemistry, 67, 145-150(1999)
○アルミニウム陽極酸化における定電圧印加時のリーク電流と帝電流印加時の電位オーバーシュートの関係（共著）,Electrochemistry, 67,, 774-779(1999)
○アルミニウム陽極酸化における定電圧印加時のリーク電流と定電流印加時の電位オーバーシュートの関係（共著）,Electrochemistry, Vol.67, No.7, pp.780-783(1999)
○Electrode Kinetics for Oxygen Reduction in Molten Alkali Carbonates（共著）,The Technology Reports of The Tohoku University, 50, 51-65(1985)
○溶融炭酸塩型燃料電池系のガス電極反応（共著）,表面，27, 843-856，広信社(1989)
○In Situ XRD仁科辰夫,表面技術，47, 834-838(1996)
○東北大学のキャンパスネットワークにおける「TAINS利用研究会」の活動（共著）,信学技報(TECHNICAL REPORT OF IEICE)，OFS96-66, 1-6(1997)
○溶融塩腐食環境の評価 (1) 電位 (E) - pO2-図の構築とその利用 仁科辰夫,電気化学，66, 253-259(1998)
○エレクトロキャタリシスの展望と応用、第7章 溶融炭酸塩型燃料電池系のガス電極反応−エレクトロキャタリシスの観点から−、p.225-257（共著）,アイピーシー(1990)
○Use and Applications of Electrochemical Impedance Techiniques ―電気化学インピーダンス測定の原理と応用―（共著）,東陽テクニカ(1991)
○溶融塩・熱技術の基礎、第9.2章 MCFCの原理，p.228-232（共著）,アグネ技術センター(1993)
○Electroreduction Mechanism of Oxygen in Molten Alkali Carbonate, PROCEEDINGS OF THE SECOND JAPAN-CHINA BILATERAL CONFERENCE ON MOLTEN SALT CHEMISTRY AND TECHNOLGY AND THE TWENTIETH SYMPOSIUM ON MOLTEN SALT CHEMISTRY OF JAPAN, 111-114（共著）,電気化学会(1988)
○Electrochemical Analysis of Oxygen Reduction Path at Au Flag Electrode and Sintered Au Spheres Electrode, Proceedings of the Second Symposium on Molten Carbonate Fuel Cell Technology, Proceedings Vol. 90-16, p.438-453（共著）,The Electrochemical Society(1990)
○EIS Studies of Oxygen and Hydrogen Electrode Reactions in Molten Carbonates, Proceedings of the Symposium on High Temperature Electrode Materials and Characterization, Proceedings Vol. 91-6, p.239-256（共著）,The Electrochemical Society(1991)
○Effect of Hydrogen Sulfide on Kinetics of Hydrogen Oxidation in Molten Alkali Carbonate, Molten Salt Chemistry and Technology, Materials Science Forum, Vol. 73-75, p.756-771 （共著）,Trans Tech Publications, Switzerland(2001)
○Studies on Pressurized Oxygen Electrode Reaction in Molten Alkali Carbonate. Molten Salt Chemistry and Technology, Materials Science Forum, Vol.73-75, p.773-778 （共著）,Trans Technology Publication, Switzerland, Vol.73-75, p.773-778(2001)
○Electrode Kinetics and Modeling of Oxygen Reduction in Molten Carbonate Media, The International Fuel Cell Conference Proceedings, p.189-192（共著）,NEDO(1992)
○Electrochemical Corrosion Studies of Fe-based Ni and Cr Alloys in Molten Alkali Carbonates, Proceedings of the Fourth Japan-China Bilateral Conference on Molten Salt Chemistry and Technology, p.30-33（共著）,電気化学会(1992)
○Electrochemical Study of Corrosion Behavior of Iron-based Nickel and Iron-based Chromium Alloys, Proceedings of the Third Symposium on Molten Carbonate Fuel Cell Technology, Proceedings Vol. 93-3, p.264-277（共著）,The Electrochemical Society(1993)
○Impurity Effect on Gas Electrode Reaction in Molten Carbonate Media, Proceedings of the Third Symposium on Molten Carbonate Fuel Cell Technology, Proceedings Vol.93-3, p.292-308（共著）,The Electrochemical Society(1993)
○Kinetic and Material Studies in Molten Alkali Carbonates under Pressurized Cathode Gas Environment, Proceedings of the Third Symposium on Molten Carbonate Fuel Cell Technology, Proceedings Vol.93-3, p.368-384（共著）,The Electrochemical Society(1993)
○Gas Solubility and Diffusivity of H2, CO2 and O2 in Molten Alkali Carbonates, Proceedings of the International Symposium on Molten Salt Chemistry and Technology, Proceedings Vol.93-9, p.424-435（共著）,The Electrochemical Society(1993)
○Corrosion Studies of Fe-based Cr Alloys Containing Al in Molten Carbonates, Proceedings of the International Symposium on Molten Salt Chemistry and Technology, Proceedings Vol.93-9, p.436-445（共著）,The Electrochemical Society(1993)
○DEVELOPMENT ON CORROSION RESISTIVE ALLOYS AND CONDUCTIVITY MEASUREMENTS OF CORRODED SCALE ON MOLTEN CARBONATE FUEL CELL COMPONENTS, The Second International Fuel Cell Conference Proceedings, p.185-188（共著）,NEDO(1996)
○CHARACTERIZATION OF AN 100 cm2 CLASS MOLTEN CARBONATE FUEL CELL WITH CURRENT INTERRUPTION, Proceedings of the Fourth International Symposium on Carbonate Fuel Cell Technology, Proceedings Vol.97-4, p.92-100（共著）,The Electrochemical Society(1997)
○ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY OF AN 100 cm2 CLASS MOLTEN CARBONATE FUEL CELL, Proceedings of the Fourth International Symposium on Carbonate Fuel Cell Technology, Proceedings Vol.97-4, p.101-111（共著）,The Electrochemical Society(1997)
○SOLUBILITY OF IN SITU OXIDIZED NiO IN (Li+Na)CO3 MELTS UNDER PRESSURIZED OXIDANT GAS CONDITION, Proceedings of the Fourth International Symposium on Carbonate Fuel Cell Technology, Proceedings Vol.97-4, p.436-442（共著）,The Electrochemical Society(1997)
○The Function of Carbon as Conductive Agent for Primary and Secondary Batteries（共著）,Progress in Batteries & Battery Materials, 17, 242-244(1998)
○Propozal for an accurate and rapid international electrochemical test for various battery materials using T-M cell(PART.2):Rechargeability of EMD containing Bi2O3 in KOH（共著）,Progress in Batteries & Battery Materials, V.17, N., pp.245-255(1998)
○Propozal for an accurate and rapid international electrochemical...(PART.3):The charging/discharging characteristics of LiMn2O4 as the cathode for Lithium secondary battery The effect of combination of current collector and electrolyte（共著）,Progress in Batteries & Battery Materials, V.17, N., pp.256-264(1998)
○Propozal for an accurate and rapid international electrochemical test for various battery materials using T-M cell(PART.4): SEM observation of LiMn2O4 positive electrode(JEC No.3) before and after the charging/discharging test in organic electrolyte（共著）,Progress in Batteries & Battery Materials, V.17, N., pp.265-272(1998)
○Charge-discharge Characteristics of LiMn2O4 as The Cathode for Lithium Secondary Battery -Effect of Cathode Particle Size-（共著）,Progress in Batteries & Battery Materials, 17, 273-275(1998)
○WHAT IS THE TRUE FUNCTION OF CARBON AS CONDUCTIVE ADDITIVE FOR LITHIUM SECANDARY BATTERIES?, Proceedings of The Second Japan-France Joint Seminar on Lithium Batteries, 66-75（共著）,電気化学会(1998)
○Control of Oxide Film Conductivity by Means of Hetero-Contact Technique, Proceedings of International Open Seminar -Design Optimization and Advanced Material Development for Molten Carbonate Fuel Cell-, 10-17（共著）,NEDO(1999)
○What Is the True Function of Carbon as a Conductive Additive for Primary and Secondary Batteries?（共著）,ITE Battery Letters, Vol. 1, No.1, pp.33-38 (1999)
○Proposal of An Accurate and Rapid International Electro-chemical Test for Various Battery Materials using T-M Cell (Part. 5): Discharging Kinetics of EMD in KOH aqueous so-lution.（共著）,ITE Battery Leters, Vol.1, No.1, pp.39-42(1999)
○CONDUCTIVITY CONTROLLING OF OXIDE SCALE ON CORRODED METAL COMPONENTS BY APPLYING HETERO-CONTACT TECHNIQUE, Proceedings of the Fifth International Symposium on Carbonate Fuel Cell Technology, Proceedings Vol.99-20, p.142-149（共著）,The Electrochemical Society(1999)
○Impurity Effect in Aluminum Cathode Current Collector on Charging/Discharging Performance of Lithium Secondary Battery, Proceedings of the International Symposium on Lithium Batteries, Proceedings Vol.99-25, p.719-729（共著）,The Electrochemical Society(2000)
○リチウム二次電池の性能評価の標準化 （共著）,山形大学紀要(工学),26, No.1, p.25-32.(2000)
○実践的見地からのシラバスデータベース開発（共著）,山形大学紀要(工学), 26, No.1, p.47-52(2000)
○山形大学シラバス処理システムの稼動状況の分析（共著）,山形大学紀要(工学) 26 pp.53-57(2000)
○Electrical Conductivity of Li2CO3-Na2CO3-K2CO3 Mixtures Containing Al2O3 in the Vicinity of Their Eutectic Point, Memoirs of the Tohoku Institute of Technology Ser.I: Science and Engineering, 21, p.11-19（共著）,Tohoku Institute of Technology(2001)
ＵＲＬ
http://www.geocities.co.jp/CollegeLife-Library/2614/